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"Sridevi still the same spontaneous and lovely..!!," Bachchan said on micro-blogging site twitter.
The two were last paired in the 1992 hit film `Khuda Gawah`. Before that, they were seen together in films like `Inquilaab` and `Akhree Rasta`.
Big B and Sridevi will star in director R Balki`s wife Gauri Shinde`s directorial debut film, `English Vinglish`.
"Shooting today with the effervescent SriDevi after eternity almost for R Balki`s wife`s directed film `English Vinglish," Bachchan said.
Big B and Balki have worked together in films like `Cheeni Kum` and `Paa`.
The film, which is touted as Sridevi`s comeback to Bollywood will see her essay the role of a housewife, who enrolls for a spoken English course to impress her husband and family. Big B will be seen making a special appearance in the film.
Sridevi was last seen in a full-fledged role in 1997 film `Judaai` with Anil Kapoor and Urmila Matondkar.